Place a rack in the center of the oven. Turn the oven on to broil and let it heat about 5 minutes. Line a baking sheet with aluminum paper and coat with cooking spray.
Place the broccoli florets in a bowl, then sprinkle in the minced garlic and drizzle on the olive oil. Mix thoroughly to coat the florets evenly. Sprinkle with a generous pinch of sea salt and toss again.
Transfer to the baking sheet and broil for 8 minutes. After 4 minutes, turn the broccoli florets so they broil all around. Once done, the broccoli will be crisp tender with charred bits. Remove from the oven and keep warm until ready to serve.
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